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DRUGS – Page 5 – EUREKAMOMENTS IN ORGANIC CHEMISTRY

Coenzyme Q10

Coenzyme Q10 2-[(2E,6E,10E,14E,18E,22E,26E,30E,34E)-3,7,11,15,19,23,27,31,35,39-decamethyltetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl]-5, 6-dimethoxy-3-methylcyclohexa-2,5-diene-1,4-dione Coenzyme Q10 (ubiquinone-10, CoQ10, CoQ, Q10 or simply Q) is aubiquinone containing 10 isoprenoid units. First discovered in 1957 by Crane et al. [1], its chemical structure was determined by Karl Folkers [2], who later won the Priestley medal from the American Chemical Society. This oil-soluble, vitamin-like micronutrient forms part of the electron transport chain which, in the process of… Continue reading Coenzyme Q10

“Crystal-clear” method distinguishes between glass and fluids

The colloids that were used for the model: particles, each with a diameter of approximately 150 nm, suspended in water. The solid nucleus consists of the plastic polystyrene, the surrounding shell of a thermosensitive poly(N-isopropyl-acrylamide) network. By lowering the temperature, each individual particle’s volume—and, by definition, its packing density—can be increased. Photo: HZB/M. Siebenbürger Many… Continue reading “Crystal-clear” method distinguishes between glass and fluids

Fluoride’s Unexpected Role In Photocatalysis-Materials: Acid’s surface residue, not just the catalyst, should get credit

Using HF in TiO2 synthesis (left) changes the crystals’ morphologies and facets relative to an HF-free method (right), as seen in these TEM images, and may unexpectedly alter the crystals’ catalytic properties. Credit: ACS Catal read all at http://cen.acs.org/articles/91/i21/Fluorides-Unexpected-Role-Photocatalysis.html Share this:

Gugulipid, an Extract of Ayurveda Medicine Plant Commiphora Mukul as a Potent Agent for Cancer Chemoprevention and Cancer Chemotherapy

E-Guggulsterone Z-Guggulsterone http://www.omicsonline.org/2161-0444/2161-0444-2-e105.php?%20aid=9899 Citation: Xiao M, Xiao D (2012) Gugulipid, an Extract of Ayurveda Medicine Plant Commiphora Mukul as a Potent Agent for Cancer Chemoprevention and Cancer Chemotherapy. Med chem 2:e105. doi:10.4172/2161-0444.1000e105 Department of Urology, University of Pittsburgh Cancer Institute, University of Pittsburgh School of Medicine, University of Pittsburgh, Pittsburgh, Pennsylvania 15232, USA Gugulipid (GL), an extract of Commiphora mukul, has been… Continue reading Gugulipid, an Extract of Ayurveda Medicine Plant Commiphora Mukul as a Potent Agent for Cancer Chemoprevention and Cancer Chemotherapy

Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)

  Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)Alejandro J. Cagnoni, Oscar Varela, María Laura Uhrig and José Kovensky European Journal of Organic Chemistry Volume 2013, Issue 5, pages 972–983, February 2013 Article first published online: 13 DEC 2012 | DOI: 10.1002/ejoc.201201412 http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201201412/abstract Ruthenium-catalyzed cycloaddition of… Continue reading Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)

Immunosuppressant Drug Rapamycin Helps Preserving Female Fertility

Sirolimus (INN/USAN), also known as rapamycin, is an immunosuppressant drug used to prevent rejection in organ transplantation; it is especially useful in kidneytransplants. It prevents activation of T cells and B cells by inhibiting their response tointerleukin-2 (IL-2). A macrolide, sirolimus was discovered by Brazilian researchers as a product of the bacterium Streptomyces hygroscopicus in a soil sample from Easter Island[1] — an island also known as Rapa Nui.[2] It was approved by the… Continue reading Immunosuppressant Drug Rapamycin Helps Preserving Female Fertility

AT13148, Drug Blocks Multiple Cancer Causes

AT13148 AT13148 is a multi-AGC kinase, ATP-competitive inhibitor, identified utilizing high-throughput X-ray crystallography and fragment-based lead discovery techniques. AT13148 caused substantial blockade of AKT, p70S6K, PKA, ROCK and SGK substrate phosphorylation and induction of apoptosis in both a concentration and time-dependent manner in cancer cells with clinically relevant genetic defects both in vitro and in… Continue reading AT13148, Drug Blocks Multiple Cancer Causes

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Bedaquiline(Sirturo, TMC207 or R207910) FDA approves 1st new tuberculosis drug in 40 years

  (1R,2S)-1-(6-Bromo-2-methoxy-3-quinolyl)-4-dimethylamino-2-(1-naphthyl)-1-phenyl-butan-2-ol, cas no 654653-81-3 Bedaquiline FDA approves 1st new tuberculosis drug in 40 years The Food and Drug Administration on Monday approved a Johnson & Johnson tuberculosis drug that is the first new medicine to fight the deadly infection in more than four decades. Bedaquiline (also known as Sirturo, TMC207 or R207910) is an diarylquinoline anti-tuberculosis drug, which was discovered… Continue reading Bedaquiline(Sirturo, TMC207 or R207910) FDA approves 1st new tuberculosis drug in 40 years

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