Bingel fullerene The Bingel reaction in fullerene chemistry The Bingel reaction in fullerene chemistry is a fullerene cyclopropanation reaction to a methanofullerene first discovered by C. Bingel in 1993 with the bromo derivative of diethyl malonate in the presence of a base such as sodium hydride or DBU.[1] The preferred double bonds for this reaction on the fullerene surface are the shorter bonds at the junctions of two hexagons (6-6 bonds) and the driving… Continue reading The Bingel reaction in fullerene chemistry
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Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)
Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)Alejandro J. Cagnoni, Oscar Varela, María Laura Uhrig and José Kovensky European Journal of Organic Chemistry Volume 2013, Issue 5, pages 972–983, February 2013 Article first published online: 13 DEC 2012 | DOI: 10.1002/ejoc.201201412 http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201201412/abstract Ruthenium-catalyzed cycloaddition of… Continue reading Efficient Synthesis of Thiolactoside Glycoclusters by Ruthenium-Catalyzed Cycloaddition Reaction of Disubstituted Alkynes on Carbohydrate Scaffolds (pages 972–983)