Ângela C. B. Neves, Mário J. F. Calvete, Teresa M. V. D. Pinho e Melo and Mariette M. Pereira
Article first published online: 18 SEP 2012 | DOI: 10.1002/ejoc.201200709
 |
The most relevant results relating to the development and use of catalysts supported on mesoporous materials, hydrotalcite, carbon materials, and nanoparticles for metal-catalyzed hydroformylation of olefins reported over the last five years are reviewed. The results are analyzed with particular regard to reusability and leaching issues.
European Journal of Organic ChemistryVolume 2012, Issue 32, pages 6309–6320, November 2012 AbstractOlefin hydroformylation is a widely used process, both on large scales and in fine chemistry, with catalyst reuse still being one of the main objectives. In recent years, developments in the immobilization of catalysts on solid supports that enable their recovery and reuse when applied in catalytic hydroformylations of aromatic and aliphatic olefins have resulted in a boost in the field of heterogeneous catalysis. This review presents the most relevant results reported over the last five years with regard to the development and use of supported catalysts in mesoporous materials, hydrotalcite, carbon materials, and nanoparticles for catalytic hydroformylation of olefins. A critical analysis of the results, especially in the context of reusability and leaching issues, is presented.
|
