\u00a0<\/h2>\n

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References :<\/h2>\n\n\n\n\n

J. Am. Chem. Soc.<\/em> 1964<\/strong>, 86<\/em>, 962. (10.1021\/ja01059a072<\/a>)<\/td>\n<\/tr>\n

J. Am. Chem. Soc.<\/em> 1964<\/strong>, 86<\/em>, 3157. (10.1021\/ja01069a041<\/a>)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n <\/div>\n SYNTHESIS OF CUBANE<\/div>\n <\/div>\n <\/div>\n <\/div>\n NBS<\/div>\n <\/a><\/div>\n CCl4<\/sub><\/div>\n wohl ziegler rxn<\/em><\/p>\n <\/p>\n Br2<\/sub><\/p>\n <\/a><\/div>\n Pentane, CH2<\/sub>Cl2<\/sub> \n0 to 10 \u00b0C<\/p>\n<\/div>\n <\/p>\n Et2<\/sub>NH<\/p>\n <\/a><\/div>\n Et2<\/sub>O \n-20 \u00b0C, 40 % (3 steps)<\/p>\n Diels alder rxn<\/em><\/p>\n<\/div>\n <\/p>\n (CH2<\/sub>OH)2<\/sub>, TsOH<\/p>\n <\/a><\/div>\n PhH \nReflux<\/p>\n<\/div>\n <\/p>\n HCl<\/p>\n <\/a><\/div>\n H2<\/sub>O \n85 % (2 steps)<\/p>\n<\/div>\n <\/p>\n h\u03bd<\/p>\n <\/a><\/div>\n MeOH \n95 %<\/p>\n<\/div>\n <\/p>\n KOH<\/p>\n <\/a><\/div>\n H2<\/sub>O \nReflux, 95 %<\/p>\n Favorskii rxn<\/em><\/p>\n<\/div>\n <\/p>\n SOCl2<\/sub><\/p>\n <\/a><\/div>\n<\/div>\n <\/p>\n t-BuOOH, Pyr<\/p>\n <\/a><\/div>\n Et2<\/sub>O \n95 % (2 steps)<\/p>\n<\/div>\n <\/p>\n \n <\/a><\/div>\n Cumene \n152 \u00b0C, 55 %<\/p>\n<\/div>\n <\/p>\n H2<\/sub>SO4<\/sub><\/p>\n <\/a><\/div>\n H2<\/sub>O \n95 %<\/p>\n<\/div>\n <\/p>\n KOH<\/p>\n <\/a><\/div>\n H2<\/sub>O \nReflux, 55 %<\/p>\n Favorskii rxn<\/em><\/p>\n<\/div>\n <\/p>\n SOCl2<\/sub><\/p>\n <\/a><\/div>\n<\/div>\n <\/p>\n t-BuOOH<\/p>\n <\/a><\/div>\n Et2<\/sub>O \n98 % (2 steps)<\/p>\n<\/div>\n <\/p>\n \n <\/a><\/div>\n Diisopropylbenzene \n150 \u00b0C, 30 %<\/div>\n<\/div>\n <\/p>\n <\/a><\/p>\n","protected":false},"excerpt":{"rendered":" CubaneCubane (C8H8) is a synthetic hydrocarbon molecule that consists of eight carbon atoms arranged at the corners of a cube, with one hydrogen atom attached to each carbon atom. A solid crystalline substance, cubane is one of the Platonic hydrocarbons. It was first synthesized in 1964 by Philip Eaton, a professor of chemistry at the… Continue reading CUBANE SYNTHESIS<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3,4],"tags":[143,144],"_links":{"self":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/98"}],"collection":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/comments?post=98"}],"version-history":[{"count":6,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/98\/revisions"}],"predecessor-version":[{"id":151,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/98\/revisions\/151"}],"wp:attachment":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/media?parent=98"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/categories?post=98"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/tags?post=98"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}