16085931<\/a>.<\/li>\n<\/ol>\n<\/p>\n
Scheme 1.\u00a0Stereoselective synthesis of\u00a0E<\/em>-guggulsterone (1<\/strong>) from 4-androsten-3,17-dione (5). (i) CH(OEt)3<\/sub>,\u00a0p<\/em>-TSA, THF\/EtOH, quantitative; (ii) EtPPh3<\/sub>Br,\u00a0t<\/em>-BuOK, THF, reflux; (iii) HCl, THF, 95% from 6; (iv) SeO2<\/sub>,\u00a0t<\/em>-BuO2<\/sub>H, 90%; (v) (COCl)2<\/sub>, DMSO, Et3<\/sub>N, CH2<\/sub>Cl2<\/sub>, 85%<\/p>\n<\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"E-Guggulsterone Z-Guggulsterone http:\/\/www.omicsonline.org\/2161-0444\/2161-0444-2-e105.php?%20aid=9899 Citation:\u00a0Xiao M, Xiao D\u00a0(2012) Gugulipid, an Extract of\u00a0Ayurveda\u00a0Medicine Plant\u00a0Commiphora Mukul\u00a0as a Potent Agent for Cancer Chemoprevention and Cancer Chemotherapy. Med chem 2:e105. doi:10.4172\/2161-0444.1000e105 Department of Urology, University of Pittsburgh Cancer Institute, University of Pittsburgh School of Medicine, University of Pittsburgh, Pittsburgh, Pennsylvania 15232, USA Gugulipid (GL), an extract of\u00a0Commiphora mukul, has been… Continue reading Gugulipid, an Extract of Ayurveda Medicine Plant Commiphora Mukul as a Potent Agent for Cancer Chemoprevention and Cancer Chemotherapy<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[13,19],"tags":[146,149,143],"_links":{"self":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/610"}],"collection":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/comments?post=610"}],"version-history":[{"count":8,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/610\/revisions"}],"predecessor-version":[{"id":619,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/610\/revisions\/619"}],"wp:attachment":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/media?parent=610"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/categories?post=610"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/tags?post=610"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}