Carbon dioxide is an important carbon source in the atmosphere and is \u201cproblematic\u201d toward the activities of human beings. Although carbon dioxide is a cheap, abundant and relatively nontoxic C1 source, its chemical transformations have not been widely developed so far and are still far from synthetic applications, especially in the construction of the C\u2013C bond. This critical review summarizes the recent advances on transition-metal-catalyzed C\u2013C bond formation through the fixation of carbon dioxide and their synthetic applications (124 references).<\/p>\n

Transition-metal-catalyzed C\u2013C bond formation through the fixation ofcarbon dioxide<\/h2>\n<\/div>\n
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Kun Huang<\/a>,^{a<\/sup>\u00a0\u00a0\u00a0}Chang-Liang Sun<\/a>^{a<\/sup>\u00a0and\u00a0\u00a0\u00a0}Zhang-Jie Shi<\/a>^{a<\/sup>^{b<\/sup><\/div>\n}}
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Corresponding authors<\/p>\n<\/div>\n
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^{a<\/sup>Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871<\/div>\n<\/div>\n}
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^{b<\/sup>State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China<\/div>\nE-mail:\u00a0<\/b>zshi@pku.edu.cn<\/a><\/div>\n<\/div>\n<\/div>\nChem. Soc. Rev.<\/strong><\/i>, 2011,40<\/strong>, 2435-2452<\/div>\nDOI:\u00a0<\/strong>10.1039\/C0CS00129E<\/p>\n<\/div>\n
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<\/p>\n","protected":false},"excerpt":{"rendered":"Carbon dioxide is an important carbon source in the atmosphere and is \u201cproblematic\u201d toward the activities of human beings. Although carbon dioxide is a cheap, abundant and relatively nontoxic C1 source, its chemical transformations have not been widely developed so far and are still far from synthetic applications, especially in the construction of the C\u2013C… Continue reading Transition-metal-catalyzed C\u2013C bond formation through the fixation ofcarbon dioxide<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4,1],"tags":[18,143,55],"_links":{"self":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/1185"}],"collection":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/comments?post=1185"}],"version-history":[{"count":5,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/1185\/revisions"}],"predecessor-version":[{"id":1190,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/posts\/1185\/revisions\/1190"}],"wp:attachment":[{"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/media?parent=1185"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/categories?post=1185"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/amcrasto.theeurekamoments.com\/wp-json\/wp\/v2\/tags?post=1185"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}}